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                    <text>�INSTITUTE ON LAKE SUPERIOR GEOLOGY

April 1

2, 1955

UNIVERSITY OF MINNESOTA

Center for Continuation Study
Minneapolis i4

�UNIVERSITY OF MINNESOTA

Center for Continuation Study
Minneapolis it,.

Institute on Lake

Superior Geology

April

1 -

2,

1955

PROGRAM

8:1.5

a.

April 1, 1955
m. Auditorium, Museum of Natural Eistory
Friday

-

Carl E. Dutton, Chairman
U. S. Geological Survey, Madison, Wisconsin

Welcome:

1.

2.

3.

11.

9:00

F. E, Berger, Director, Center for Continuation Study
J. M. Nolte, Dean of University Extension
G. A. Thiel, Chairman, Department of Geology and Mineralogy
Harold L. James:

Sedimentary fades of iron-formation

10:00

Intermission (Please, no smoking in auditorium)

10:10

David White:

11:10

DiscussIon

12:00

Luncheon

Origin of the Biwabik iron-formation, Mesabi
Range, Minnesota

1:30

Burton Boyum, Gerald J. Anderson, and Tsu-Ming Han:
Progress report on the primary features of the
Negaunee iron-formation, Marquette district,
Michigan

2:30

DIscussion

3:00

Intermission

3:10

Stanley Tyler:

li.:1O

Discussion

On the origin of the Lake Superior iron ores

�UNIVERSITY OF MI1'INESOTA
Center for Continuation Study
Minneapolie 111

•"titute on Lake Superior Geo1

April 1 -

2,

1955

PROGRAM

Friday

-

April

1, 1955

6:30 p.m. Junior Ballroom, Coffman Memorial Union

0. M. Schwartz, Professor of Geology and Director, Minnesota
Geological Survey

GEOPHYSI CS IN TEE LA STJPERI OR EEGI ON

Gordon Bath, Chairman

U. S. Geological Survey

Charles E. Jahren: Some magnetic susceptibility measurements
on diamond drill cores from the Cuyuna district
Edward Thiel:

Panel

A gravity study of the

Lake Superior syncline

Discussion:

James Baisley, Chief, Geophysical Branch, U. S. Geological
Survey, Washington, D.C.; Harold Mooney, Assistant Professor
of Geophysics, University of Minnesota; George Woollard,
Professor of Geophysics, University of Wisconsin;
Lloyal 0. Bacon, Assistant Professor of Geophysics, Michigan
Institute of Mining and Technology, Houghton, Michigan; and
others.

�UMEVERSITY OF MINNESOTA
Center for Continuation Study
Minneapolis 11i

April

Superior Geology

Institute on Lake

1 -

2,

1955

PR0RAM
Saturday Morning -

April

2, 1955

9:00 a.m. Auditorium, Museum of Natural History
Carl E. Dutton and S. S. C-oldich, Co-Chairmen

(10-is minutes are allowed for presentation; 5 minutes for discussion)
1.

Robert G. Schmidt:

Stratigraphy in the central part of the Cuyuna district,
Minnes eta

2.

3.

I.

Justin Zimi, Gerald L. Brooks, Theodore Engel, and Richard Hagni:
Studies of stratified rocks occurring below the Huronian
succession in the Marquette district, Michigan

J. F. Wolff, Sr.:
N. King Huber:

Summary of the sub-divisional correlation of the Middle
Huronian iron formations of the Lake Superior district

Environmental control of sedimentary iron minerals

3.

Henry Lepp:

6.

L. C. Kilburn and HIID.B. Wilson:

7.

Alan T. Broderick:

8.

Howard Evans:

9.

Joseph P. Dobeli:
J. E. Dryden:

Nagnetite, maghemite, hematite
Pyrrhotite iron formations

Some notes on the occurrence of oxidation and
soft iron orebodies at considerable depth in
the Iron River district, Michigan

Color photographic record of drill core
Sandstone dikes in Keweenawan lavas

A near surface crystalline mass at Manson, Iowa

�U1IVERSITY OF MENNESOTA
Center for Continuation Study
Minneapolis ]A

Institute

on Lake

Superior

Geology

April 1 -

2,

1955

PROGRAM

Saturday
1:00

Afternoon -

April

p.m. Auditorium, Museum

of

2, 1955

Natural History

Carl E. Dutton and S. S. Goldich, Co-Chairmen

Megesoopic petrofabrics used in dociphering structure

1.

James W. Trow:

2.

J. M. Neilson and J. P. Dobell:

3.

F. M. Swain and N. Prokopovitch:

Ii..

James H. Zumberge:

Keweenawein felcites of the Beto Grise
Bay area

Stratigraphy of Minnesota lake deposits

Bottom coring in Lake Superior

5.

Gerald

M. Friecinian:

Progress report on the Mamainse "Diabase," Batchawana,
Ontario

6.

Gerald

E. Anderson:

The ore minerals of the copper-nickel deposits In
the Duluth gabbro

7.

Donald H. Yardley:

8.

M. P. Walls:

Geochemical exploration for nickel and copper In
northern Minnesota

The work of the Hibbing laboratory of the Division of
Land and Minerals

�UNIVERSITY OF MINNESOTA

Center for Continuation Study
Minneapolis

Institute

on Lake

i1i

April. 1 — 2, 19%

Superior Geology

THE ORE MINERALS OF THE COPPER—NICKEL DEPOSITS IN THE DULUTH GABBRO

Gerald

E. Anderson

University of Minnesota,

Minneapolis,

Minnesota

The discovery in 19L1.8 of appreciable amounts

of

copper and nickel

sulfides near the base of the Duluth gabbro south of Ely, Minnesota, has
stimulated field exploration and laboratory studies.

The present work on

the mineralogy of the sulfide mineralization is being done under the auspices
of the Minnesota Geological Survey with the aid of a fellowship sponsored
by the E

J

Longyear Company.

The principal mineralization discovered to date is restricted to a
narrow band in the gabbro near the base.

Definite paragenetic relationships

have been determined between the rock silicates, the magnetite, and the
sulfides, which in order of abundance are chalcopyrite, pyrrhotite, cubanite,
pentlandite, violarite, and pyrite—marcasite.
types of sulfide assemblages.

There appear to be two general

In some specimens relatively massive copper

sulfides predominate, whereas in others, pyrrhotite and pentlandite are
more abundant and interstitial to the silicates.
The copper—nickel mineralization is characteristic of most, if not all,
large differentiated gabbroic intrusions.

Brief consideration is given to

some hypotheses to explain the origin of the deposits.

�UNIVERSITY OF MINNESOTA
Center for Continuation Study

Minneapolis Th

Institute

April 1 —

cii Lake Superior Geology

2, l9S

PROGRESS REPORT ON THE PRIMARY FEATURES
OF THE NEGAUNEE IRON—FORMATION,
MARQUETTE DISTRICT, MICHIGAN

Burton H

Boyum,

Gerald J.

Anderson, and Tsu—Ming Han

The Cleveland—Cliffs Iron Company,

Ishpeming,

Michigan

A progress summary is presented describing the primary features of the
Negaunee iron—formation of the Marquette District, Michigan.

The Negaunee

iron—formation is distinctive because of its thickness and uniformity and
may be considered as being a single unit, by contrast with other major
iron—formations of the Lake Superior region in which two to four members
are recognized.

The general setting and the position in the Huronian sec-

tion are outlined.

Nomenclature and historical highlights are reviewed.

The subject of total thickness is developed.
A specific description of the Negaunee iron—formation is detailed.

The

lower contact with the Siamo formation •is examined relative to the "inter—

bedded argillaceous complex".
oolitic zones.

Clastic phases are shown,

together

with

Attention is given to the igneous rocks found in the

Negaunee iron—formation.

Special studies using spectrographic analyses and

oil field electric logging are presented.

The conclusion is reached that

the primary Negaunee formation is remarkably uniform and that local primary
features

cannot

be used as horizon markers for great distances, as these

features seldom extend more than one—half to one mile along the strike or
dip.

�UNIVERSITY OF MINNESOTA

Center for Continuation Study
Minneapolis iii.

April 1 — 2, 195

Institute en Lake Superior Geology

SOME NOTES ON THE OCCURRENCE OF OXIDATION AND SOFT IRON OREBODIES
AT CONSIDERABLE DEPTH IN THE IRON RIVER DISTRICT, MICHIGAN

Alan T. Broderick
Inland Steel Company, Ishpeming, Michigan

The earthy to massive hematite—goethite—limonite orebodies in the Iron
River District occur in the oxidized portions of a practically unmetamorphosed
chert—side rite iron formation.
In the writer's opinion, the structural and mineralogic evidence supports
classic theory of origin of these deposits, i.e. that they are the result
of the oxidation of siderite, the transportation and deposition of iron and
the removal of silica by circulating oxygen—bearing meteoric waters.
the

There is considerable evidence that the replacement of chert by iron
oxides and not the leaching of chert is the major ore—forming process.
The circulation has been long held to be artesian. However, since ore has
now been found at about 2000 feet vertically below ledge and through oxidation
down to nearly 3000 feet, topographic and structural arrangements which coi.d
have afforded the necessary hydraulic head have become increasingly improbable.
The writer proposes that heat introduced along the major faults as hot
water or steam provided the energy which caused the circulation. The heavy
cool column of meteoric water in a limb of iron formation cut at depth by one
of these warm channels would tend to move downward in the formation and then
rise in the heated channel. Once established, such a circulation might be
supported by heat from the wall—rocks if the geothermal gradient were steep
enough. Laboratory experiments on the solubility of silica suggest that the
silica—bearing solutions must have been warm.

The tendency of many of the orebodies to lie on structural footwalls of
either older or younger rocks indicates that another gravity—controlled mechanism must also have been operative. The writer believes that this is simply
that the solutions richest in iron, those which would be the most active in replacing the chert, would also be the heaviest and therefore would follow the
bottom of any channel and displace any lighter solutions. This density current
principle alone might be the circulation—causing force in shallow structures or
in cul—de—sac areas lying below the main thermally—stimulated circulation

channels.

In some of the Iron River mines, there is evidence of a post—oxidati.n
period of mineralization that is quite
from the original ore—forming
period. In these areas, irregular mineralized zones occur which cross the normal orebodies. These zones contain specularite, barite, rhodochrosite, quartz,
pyrite, hausrrianite, magnetite, and traces of chalcopyrite, sphalerite, and
pitchblende. These may be the result of a late resurgence of hydrothermal
fluid from the same source as that which stimulated the deep meteoric circulation, or it could be a later, completely independent invasion from a new source.
Radioactive age determination on traces of pitchblende indicate the latter.

distinct

�UNIVERSITY OF MINNESOTA

Center

for Continuation Study
Minneapolis 1l

Institute nn Lake Superior Geol

April 1 — 2, 195S

SANDSTONE DIKES IN KEWEENAWAN LAVAS

Joseph P

Dobell

Michigan College of Mining and Technology
Houghton, Michigan
Sandstone

dikes occur in a Keweenawan flow which crops out

at

Bete

Grise Bay on the east side of the Keweenaw Peninsula of Upper Michigan.
Three parallel dikes

fifteen

feet apart were noted.

The thickness ranges

from an inch to eight inches and the length is from seven to eight hundred.

feet.

Two

of

the dikes are a few feet beneath the surface of Lake Superior

and the third occurs just

above the waterline.

The elastic material was injected or wind blown
which parallel the Keweenaw fault.

The dikes are

into

open fractures

megascopically

and

rnineralogicafly similar to the Upper Cambrian Jaccbsville sandstone.

�UNIVERSITY OF MINNESOTA

Center for Continuation Study
Minneapolis it
April 1 — 2,

Institute on Lake Superior Geology

l9S

A NEAR SURFACE CRYSTALLINE MASS AT MANSON, IOWA

J. E. Dryden
Department

of Geology, State University of Iowa, Iowa City, Iowa

A near—surface occurrence of crystalline rock has been discovered at
Manson, Iowa, 17 miles west of Fort Dodge, Iowa.

Water well records indicate

that it is a flat—topped elliptial mass with an area of approximately
square miles.

It has steeply dipping sides and rises to within 90 feet

of the surface under a cover of glacial drift.

a disturbed area measuring l miles by 2L

The mass is surrounded by

miles.

The rock has been cored to a depth of I90 feet.

Megascopically, the

core is composed of irregularly alternating light gray gneiss, coarse pink
and white feldspar, chioritized breccia and chlorite schist with magnetite.

A study

of

selected thin sections suggests an original syenite gneiss

extensively replaced by albite and

orthoclase.

The entire rock is altered

to kaoliriite and breccjated zones are altered to chlorite.
The lithology suggests that the mass is of pre—Cainbrian age.

The

disturbed area contains sediments reported to be Cretaceous in age.
A

cross section of the area reveals evidence of faulting, but the

relationship of the faults to the crystalline structure has not been
established at this time.

�UNIVERSITY OF 1'ttNNESOTA

Center

for Continuation Study
Minneapolis 14
April 1 — 2, 1955

Lake Superior Geology

istitute

COLOR PHOTOGRAPHIC RECORD OF DRILL CORE
Howard Evans
Oliver Iron Mining, Research Laboratory, Duluth, Minnesota

The usual method of retaining one—half the drill core for permanent visual record has been supplanted by a color photographic record.
The colored photographs, supp1emexted by the core logs have been found
adequate for subsequent reference.

This was done to dispense with the

labor of splitting the core, to overcome the problem of large storage
space and to permit all the core to be available for testing purposes.
The original cost of the equipment and the continuous cost of maintain—
ing the program may seem high, but it is only about one—third the cost
of splitting and storing core.

At the present time, the photographs

from over 300,000 feet of drilling are filed in a space approximately

2' x 4

x 4'. If

this record had been kept as split core it would

have occupied a building 100' x 120' x 10' high, and this space would
allow very little room to work.

If storage area is limited some of

the core eventually will have to be discarded to make room for new core
arriving.

With the colored photographic record of the drill core, the

filing can continue indefinitely without running out of space.

It is

also more convenient, when there is a desire to review the core from a
drill hole, to be able to quickly select the slide from the file, rather
than carry on an extended search for it in a storage house and transport
it to the examination site.

�UNIVERSITY OF MINNESOTA
for Continuation Study
Minneapolis 34

Center

stitute

April 1 — 2, 1955

on Lake Suerior Geology

PROGRESS REPORT ON TRE MANAINSE "DIABASEtt,
BATCHAWANA, ONIARIO.

Gerald N. Friedman

Saalt

Ste. Marie, Ontario, Canada

The Mamainse YtDiabasetl

is

located about 3

miles

north of Sa.tilt

Ste. Marie in the District of Algoma within about six miles of the east
The area is one of the most rugged in Ontario.
shore of Lake Superior.
The Mamainse "Diabase" forms a high plateau with an average elevation
of about 1600 to lOO feet and is intersected by deep fault— and joint—
controlled valleys. The Griffin Lake diabase intrusion, which postdates the Mamainse "Diabase", underlies an area of at least three square
miles at the eastern margin of the Mamainse "Diabase" and rises to an
elevation of 2100 feet towering about 1400 feet above Lake Superior.
The

Mamainse "Diabase" is

a metadiabase and metabasalt

composed of

plagioclase (AnA5O) and hornblende with locally abundant epidote and
chlorite. Its texture ranges from ophitic and poikilophitic to basaltic;
metabasalts of porphyritio texture were noted but are rare. Pillow
structures suggest deposition in a submarine environment.
A complex series of metamorphosed lavas and sediments, and siliceous
iron ore is interbedded with the Maniainse "Diabase" near its northern
and southern margins. This complex sequence was overlain by the main
mass of the Mamainse "Diabase" prior to folding. The rocks maintain
general east—west to N 60°E strike and have a steep dip. Granite
dikes locally cut up the "diabase" and interbedded formations and are
Ln turn cut by later diabase dikes which are probably equivalent to
Moore's Lower Keweenawan. Faults and joints of several generations are
irominent and are locally mineralized with cobaltite, chalcopyrite,
rite, pyrrhotite, molybdenite, carbonate and quartz veins.

The Griffin Lake diabase intrusion is mostly composed of plagio—

e (An502) and subcalcic augite (2 V= 35—44°). Quartz and
opegnatite are abundantly disseminated through the rocks, secondary
nblende is locally prominent and epidote has been noted.

�UNIVERSITY OF MINNESOTA
Center for Continuation Study
Minneapolis 14
April 1 —

istitute on Lake Superior Geo1o

2, 1955

ENVIRONMENTAL CONTROL OF SEDIMENTARY IRON MINERALS
N. King I-tuber

U. S. Geological Survey, Iron Mountain, Michigan

A recontly developed Eh—pH (th =

bility

oxidation

diagram for hematite, siderite and

potential) iron mineral

pyrite

has been extended to

Lude raagnetite through the utilization of free enerr data for these

als in addition to the solubility data previously used.

Physical—

a1 data supports the probability of primary (or diagenetic)
bite in sedimentary

iron—formations

as suggested by field evidence.

The chemical environments, as indicated by the Eh—pH stability
diagram are sunmarized as follows:

Hematite: Requires oxidizing environment, although stable under
moderately reducing conditions above pH of approximately 5.
Siderite: Stable under intermediate Eh conditions, and apparently
only below pH of approximately 6.5.

Magnetite:

Stable under moderately reducing conditions at pH values

of approximately 6

or

above.

Pyrite: Moderate to strongly reducing environment through normal
pH range.

�UNIVERSITY OF MINNESOTA
Continuation Study

Center for

Minneapolis hi.

nstitute

April 1 —

on Lake Superior Geology

2,

1955

SOME MAGNETIC SUSCEPTIBILITY MEASUREMENTS ON
DUMOND DRILL CORES FROM THE CUYtJNA DISTRICT

Charles E • Jahren

U. S. Geological Survey,

Austin

Junior College, Austin, Minnesota

Measurements of magnetic susceptibility of 57 cores from diamond
drilling in the Cuyuna District were made as part of a geophysical study
by the U. S. Geological Survey and the Minnesota Geological Survey.
Values of susceptibility are

calculated

from the readings of an alternating

current deviation test bridge, slightly modified from commercial design,
and the calculated values are tabulated against footage and generalized
geologic logs.

Susceptibilities of cores with similar

where this seems feasible.
readings
and

from adjacent

values are averaged

The problems of interpreting scattered

core smples, the effects of varying core recovery,

the compari son of values from oxidized and unoxidized core

discussed.

are

�UNIVERSITY OF IffNNESOTA

Center for Continuation Study
Minneapolis 14

stitute on Lake orior

Gel

April

1 — 2., 1955

SEDIMENTaRY FACIES OF IRON—FORMATION

Harold L. James
U. S. Geological Survey, Menlo Park, California
The sedimentary iron—formations in the Lake Superior region can be
divided on the basis of the dominant original iron mineral into four prinsulfide, carbonate, oxide, and silicate. As chemical sedi—
cipal facies:
raents, these rocks reflect certain aspects of the chemistry of the deposi—
tional environxients. The major control, at least for the sulfide, carbonate,
and oxide types, was the oxidation potential. The evidence indicates that
deposition took place in restricted basins, which were separated from the
open sea by thresholds that inhibited free circulation and permitted development of abnormalities in oxidation potential and water composition.

The sporadic distribution of metamorphism and of later oxidation permits
primary fades on the basis of unoxidized, essentially
unnetamorphosed material. The sulfide facies is represented by black slates

description of the

in which pyrite may make up as much as 40 percent of the rock. The free—
carbon content of these rocks typically ranges from 5 to 15 percent, indicating that ultra—stagnant conditions prevailed during deposition. Locally,
The carbonate facies
the pyritic rocks contain layers of iron—rich carbonate.
consists, in its purer form, of interbedded iron—rich carbonate and chert.
It is a product of an environment in which oxygen concentration was sufficiently high to destroy most of the organic material but not high enough to
facios is found as two
permit formation of ferric compounds.
principal types, one characterized by magnetite and the other by hematite.

The cie

Both minerals appear to be of primary origin. The magnetite—banded rock is

one of the dominant lithologies in the region; it consists typically of
magnetite interlayered with chert, carbcnate, or iron silicate, or combinations
of the three. Its mineralogy and association suggest origin under weakly

oxidizing to moderately reducing conditions. The hematite—banded rocks consist of finely crystalline hematite interlayered with chert or jasper. Oolitic
structure is common. This facies doubtless accumulated in a strongly oxidiz-

ing, probably nearshore, environment similar to that in which younger hematitic
ironstones such as the Clinton oolite were deposited. The licate faci
contains one or more of the hydrous ferrous silicates (greenalite, minnesotate,
stilpnomelane,

chlorite) as a major constituent.
Granule structure, similar
to that of glauconite, is typical of some varieties; others are nongranular
and finely laminated. The most common association of the silicate rocks is
with either carbonate— or magnetite—bearing rocks, which suggests that the
optimum conditions for deposition ranged from slightly oxidizing to slightly
reducing. AU of these rocks show evidence of post—deposition, pre—lithifica—
tion changes (diagenesis), which in general have produced minerals characteristic of one step lower in the oxidation—potential scheme.

�UNIVERITY OF ffNNESOTA

Center for Continuation Study
Minneapolis

Institut on Lake Superior ology

14

April

1 — 2, 1955

Harold L. James
Page 2

The generalized facies characteristics of the iron—formations in the
principal Lake Superior districts are summarized as follows:
1. Mesabi. Most of the Biwabik iron—formation is of the oxide facies,
principally magnetite—banded, with a large amount of granular silicate rock.
White's study has shown that the oxide—silicate rocks of the main Mesabi
grade westward into carbonate and sulfide facies.
2. Ouyuna.
Principally silicate and carbonate rocks, verging toward
the sulfide facies (which accounts for the high—phos, high manganese ores).

Similar to the Mesabi, with magnetite—banded oxide facies
3. Gogebic.
and silicate facies predominant. Magnetite—banded rock grades locally into
carbonate iron—formation, but much of the carbonate in the rocks can be shown
to be the result of diagenesis.
4. Marquette. Lower part of the Negaunee iron—formation is carbonate
fcies, which grades upward into silicate facies and that in turn to rock of
the oxide facies that forms the uppermost part of the formation.

The Vulcan iron—formation is almost entirely of the oxide
5. Menominee.
facies; the lower member appears to be principally magnetite-banded rock; the
upper member is principally hematite—banded rock.
6. Iron River—Crystall Falls district.
The main iron—formation is
carbonate facies, which is underlain by and gradational into a 50—foot black
slate bed that contains 35—40 percent pyrite.

The relationship between the iron—rich rocks and volcanism, stressed by
many, is believed to be structural, not chemical: in the Lake Superior
region both iron—deposition and volcanism are related to geosynclinal develop—
rient during Huronian time. In Michigan, the lower Huronian rocks are iron—
poor quartzite and dolomite-—typical "stable—shelf" deposits; most of the
upper Huronian consists of iron—poor grayiacke and slate with associated
volcanic rocks—a typical "geosynclinal" assemblage. Thus the iron—rich
beds of the middle Huronian and lower part of the upper Huronian were deposited
during a trasitional stage in structural history. The major environmental
requirement for deposition of iron—formation is the closed or restricted basin;
this requirement coincides in time with what would be a normal stage in evolu—
tion of the geosyncline: namely, structural development of offshore buckles
or swells that subsequently develop into island arcs characterized by volcanism.

�UNIVERSITY OF 1INNESOTA
Center for Continuation Study
Minneapolis iL'.

stitute

April 1 — 2,

on Lake Superior Geology
FYRRHOTITE IRON FORMATIONS
L. C. Kilburn and H. D. B. Wilson
University of Manitoba, Winnipeg, Canada

Large numbers of pyrrhotite iron formations are being discovered in
the

Canadian shield by airborne magnetic and electromagnetic surveys.

One

common type of pyrrhotite iron fonnation consists of banded pyrrhotite—
magnetite

mixtures in banded cherts and tuffs.

other types

of

These deposits like many

pyrrhotite deposit are barren of other base metal mineralization.

Laboratory experiments show that H23 reacts with magnetite and converts
it to pyrrhotite at temperatures as low as LOO° C.

Iron silicates are con-

verted in part to pyrrhotite at somewhat higher temperaturs.
It is proposed that this type of banded pyrrhotite—magnetite deposit is
a normal cherty iron formation which has been metamorphosed by heat and
reaction with a sulphur—bearing gas, possibly H2S, to produce pyrrhotite
from some of the magnetite and possibly from some of the iron—bearing
silicates.

�UNIVERSITY OF i1INNESOTA
Center for Continuation Study
Minneapolis iL

April

Thstitute on Lake Superior Geology

1 —

2, 19SS

MAGNETITE, MAGHEMITE, HEMATITE

Henry Lepp
University

of

Minnesota,

Duluth Branch,

Duluth,

Minnesota

Differential thermal analyses of magnetite specimens show that magnetite

goes through two stages of oxidation when heated in air. The first stage
occurs at temperatures between 200 and
to

S60°

C, and its intensity is related

the fineness of the specimen. The second stage begins at approximately

6°

C

It

and it is often not complete even at ioSo° C.
is suggested that the first stage is a surface phenomena involving.

the formation of maghemite (gamma Fe203) on the

amount of

maghemite

specimen,

and of

a

formed is a function of

the speed of oxidation.

magnetite nuclei.

The

the specific surface of the

The second stage results from

complete breakdown of the magnetite structure with oxidation to hematite

(alpha Fe203).
The behavior of synthetic siderite with respect to oxidation supports
the foregoing explanation for the mechanism of magnetite oxidation.
is commonly first oxidized to magnetite.

Siderite

Rapid oxidation of synthetic

siderite at moderate temperatures produces gamma

Fe203 as an end product,

whereas slow oxidation of the same material results in the formation of
alpha—Fe203.

�UNIVERSITY OF MINNESOTA

Center for Continuation Study
Minneapolis iL'.

Institute

on Lake

Superior Geology

April 1 —

2, 19SS

KEWEENAWAN FELSITES OF THE BETE GRISE RAY AREA

J.

14. Neilson and

J.

P. Dobl1

Michigan College of Mining and Technology, Houghton, Michigan

Recent field and laboratory studies have been undertaken at the
Michigan College of LiLining

and Technology

in an effort to determine the

origin of certain felsite masses in the Bete Grise Bay area of the
Keweenaw Peninsula.

The felsite masses

occur

of interbedded lava flows and conglomerates.
felsite
and

in the Keweenawan series
Earlier workers mapped the

occurrences and suggested intrusive relationships

for some bodies

extrusive relationships for others. Results of the present work in—

dicate that thc felsites are

rhyolitic differentiates of a magma which

provided the chemically—related lavas of the region, and that some felsite

masses bear intrusive relations to the older rocks while others were extruded as highly viscous flows.

Criteria are presented for the field

recognition of both types of felsitic occurrence.

�UNIVERSITY OF MINNiSOTA

Center for Continuation Study
iviinneapolis 1)4

April 1

Institute on Lake Superior Geo1ogr

—

2,

195

STRATIGRA.PHY IN THE CENTRAL PART OF
THE CUYUNA DISTRICT, ItINNESOTA

Robert G. Schmidt

U. S. Geological Survey, Washington, D. C.

(ie stratigraphy of the Cuyuna district has been shown to be much
simpler than was previously believed. Almost all of the iron ore and mangan—
iferous iron ore produced in the district is mined from one well—defined
stratigraphic unit, here referred to as the "main" iron—formation. Other

sediments may be roughly grouped as older or younger than the main iron—
formation, and the stratigraphic positions of the other rocks are usually
measured from it.

The elastic sediments are dominated b3r argillites and siltstones. Part
of the argillites older than the main iron—formation are sandy or silty,
and there are lenses of quartzite near the contact with the iron—formation.
Between 1,000 and about 2,000 feet stratigraphically below the iron—formation
fine quartz siltstones are abundant. These siltstones are the oldest rocks
that have been examined in this study.

The main iron—formation is the best—knvwn stratigraphic unit in the
district. Its lithologic variations are similar to some "typical" pre—Cambrian
iron—formations in other districts. Extensive changes in lithology and
thickness take place in short distances along the strike.
Two general lithologic types have been recognized and mapped. The
thin—bedded fades is a thinly laminated rock, which may contain any combination of chert, siderite, minnesotaite, stilpnomelane, and magnetite. The
thick—bedded Lacies is composed of chert and red and brown iron oxides. In
part of the district, the entire iron—formation is thick—bedded, in part it
is all thin—bedded, and in about one third of the area the thick-bedded facies
overlaps the thin-bedded facies and grades downward into it. Several lines
of evidence suggest——but do not prove——that the thick—bedded facies was
deposited in shallower water. In general, where the iron—formation is thin,
the thick—bedded facies is present or dominates, granular textures may be
present, and there are quartzite lenses in the adjacent older sediments.
The younger sediments are generally finer elastics, partly ferruginous
and partly carbonaceous. Tuffaceous argillites, tuffs, and lava flows make
up the 300 feet immediately overlying the main iron—formation .J The volcanic
rocks and some associated argillites, which are assumed to be reworked tuffs,
are characterized by an unusually high Ti02 content, generally 1 to )4 percent and averaging about 2 percent. This itaniferous zone can be easily
mapped even where the stratigraphic position of sediments cannot be determined
by other means. It is therefore useful in the solution of stratigraphic problems.
Part of the younger argillites is abnormally ferruginous and locally grades
into lenses of lean "upper" iron—formation. The relation of these lenses to-a
particular stratigraphic horizon is not known, but it is probable that they
are not all of the same age. They have not been found closer to the main
iron—formation than SOO feet. The transitional contacts of these lenses
contrast with the sharp contacts of the main iron—formation

.

�UNIVERSITY OF IviIINESOTA

Center for Continuation Study
Minneapolis 114.

Institute

on Lake

Superior

April

Geology

STRTIA?HY

1 —

2, 19S5

OF MINNESOTA LAKE DEPOSITS

F. M. Swain and N. Prokopovich
University of Minnesota, Minneapolis, Minnesota

Samples
been studied •

County;
County;

of

the bottom sediments of several lakes in Minnesota have
The

lakes include Minnetonka, Hennepin

Johanna, Ramsey County; Cedar,

County; Prior, Scott

Wright County; Burntside, St. Louis

and Beaver Bay area, Lake Superior. A preliminary report of the

results of

these studies will be presented.

�uNIvERsir OF MINNESOT

Center for Continuation Study
Minneapolis lLi.

Institute on Lake Superior Geology

April 1 —

2,

195S

A GRAVITY STUDY OF THE LJKE SUPERIOR SYNCLINE

Edward Thiel

University

of Wisconsin, Madison,

Wisconsin

Six years ago the Geophysics Section at Wisconsin began a program of
regional gravitational mapping in the western United States and .1aska. The
first traverses leading westward from Madison across the northern mid—contiIn some cases
nent in 19)49 detected regions of abnormally high gravity.
this "high" was flanked on both sides by gravity "lows" • As the data accumulated it became evident that the anomalous area formed a more or less linear
feature, offset in several places, extending from the Lake Superior region
southward into Kansas. On the south, the anomalous area was blanketed by
Paleozoic sediments, and the scarcity of deep boreholes made interpretation
difficult. Therefore, the cause of the anomaly was sought first at its
northern end, about Lake Superior, where the pre—Canibrian rocks outcrop,
facilitating a correlation of gravity and geology.
In the Lake Superior area the large regional anomaly is associated with
rocks of Keweenawan age. Positive Bouguer anomalies occur over the dense
lava flows of the Keweenaw Peninsula, northwestern Wisconsin, northeastern
Minnesota, and Isle Royal; these anomalies reach +60 mgals in Wisconsin and
Minnesota. The gravity "lows" occur over basins filled with low density
sediments of Upper Keweenawan age; the most striking example is the —90 mgal
low on the Bayfield Peninsula.
second thick accumulation of sedimentary
rocks is suggested. to underlie the —90 mgal low at Cinber1and. The structre
exhibited by the. Pale ozoic rocks (River Falls Syncline) in the Curaberland
region may represent only the last stage in the development of the more
fundamental Keweenawan structure at depth
Steep gravity gradients indicate the Douglas Fault. A second major
symmetric to the Douglas Fault is mapped in northwestern Wisconsin on
the opposite side of the Lake Superior Syncline. The center of the syncline
has been thrust upward between the two faults as a horst. The interruption

fault

of the positive anomaly near eUon is related to the intrusion of a granitic
mass. Further detailed geologic correlation is presented in six structure
sections along lines of gravity traverse.
An isostatic correction cannot significantly reduce the gravity differentials in the Lake Superior region. Complete local isostasy cannot
exist here, but regional isostasy which considers the "highs" and "lows"
together may prevail. A "geological correction" which takes account of
geology to a radius of 20 miles from a station and to a depth of 38,000
feet was computed for gravity stations in Wisconsin. Such a correction
accounts for the greater part of the anomalies. Any attempt to compute
variations in the thickness of crustal layers without first allowing for
the near—surface geology would have led to serious error in this region.

�UNIVERSITY OF IVaNNESOTA
Center for Continuation Study
Minneapolis it1.

Institute

on Lake Superior

April

Geology

1 —

2, l9S

MEGASCOPIC PETROFABRICS USED IN DECIPHERING STRUCTURE
James W. Trow

U. S. Geological Survey, Michigan State College, East Lansing, Michigan

Megascopic rock fabrics are integrated with lithology, gross structure,
and microscopic petrofabrics in an outline of

the

sequence of

orogenic

events of late Huronian time in a part of Dickinson County, Michigan.

The

fabrics of these Huronian and pre—Huronian rocks are compared to the fabrics
of a somewhat similar lithologic sequence of' Cambro—Ordovician and pre-

Cambrian rocks of Dutchess County, New York, described in detail in the

literature by Robert Balk, and briefly examined by the author of the
present paper.
Statistical equal—area diagrams of rock fabrics support the conclusions

that the rocks of the Dickinson County area experienced i) late-Huronian
deformation within the pattern determined largely by the anisotropism of
the pre—Huronian rocks, 2)
and

strong

following dip—slip underthrusting and ramping, 3) deformation in same

instances facilitated by the
ding and

the

strike—slip movement contemporaneous to

development of slip cleavage parallel to bed-

gneissic foliation, and L1.) metamorphism of

waning stages

of

the orogeny.

basic

intrusives during

�flTI1jSITy OF IvtENNESOTA

Center
titute

k

for Continuation Study
Minneapolis 14
April 1 — 2, 1955

prior Geology

ON THE ORIGIN OF THE LAKE SUPERIOR IRON ORES

Stanley

University

A. Tyler

of Wisconsin, Madison, Wisconsin

The origin of the Lake Superior iron ores has intrigued geologists for the
past one hundred years. Concepts pertaining to ore genesis advanced by Foster
and Whitney, Whittlesey, Lapham, Brooks, Irving and Van Hise, Van Hise and
Leith,

Gruner and Tyler are briefly summarized as a basis for discussion

Although many diverse opinions have been expressed regarding the origin
ores there seems to be more or less general agreement among the more

of the
recent

1.

workers upon

the following points:

The iron formations

of

the Lake Superior region were originally comquantities of iron

posed dominantly of silica, with important but subordinate
carbonate, iron silicate, iron oxide and iron suiphide.

2. The iron ore is largely a residual product formed by alkaline oxygen—
bearing solutions which oxidized the ferrous minerals to the ferric state and
removed the silica in solution.

.

Migration of iron and replacement has played an important part in the
development of some — perhaps many — ore bodies.
4. Fractures, faults, joints, breccia zones, bedding planes, dikes, sills
and impervious sedimentary horizons have exerted a marked control upon the path
that the ore forming solutions took through the iron formation.
5. The period of ore formation was largely if not entirely restricted to
the pre—Gsxnbrian.

In

contrast, general lack of agreement, diverse opinions and some controversy has centered around the following points:
1. Whether the solutions that oxidized the iron and leached the silica
were rising hydrothermal waters or cold descending meteoric waters.
2. Whether the silica that was leached from the iron formation during the
process of ore formation was largely in the form of chert (quartz)..:or largely
in the form of iron silicates such as ninnesotaite, stilpnomelane, chlorite
and grunerite.

Thiphasis placed upon hot waters, alkaline waters or a silicate facies of
the iron formation as necessary requisites for ore formation calls for the
most optimum conditions for ore formation. Since the time factor is unknown
it seems more probable that the ores may have developed rather slowly under
less optimum conditions. Mineralogical and chemical evidence is cited to substantiate the concept that both acid and alkaline solutions have passed through
some of the iron ore bodies of the Lake Superior region.
is

The iron formation is considered to be a peculiar sedimentary
sensitive to the presence of oxygen and to the loss of silica.

cept leads to the conclusion that the ores may have formed
under differing sets of environmental conditions.

rock which
This con-

at different times

�UNIVERSITY OF MINNESOTA
Continuation Study
Minneapolis 14

Center for

Institute

on Lake Superior Geo1

April 1

2, 1955

THE WORK OF TEE RIBBING LABORATORY OF THE
DIVISION OF LAND AND MINERAlS
M. P. Walle

Division of Land and Minerals, Department of Conservation, Ribbing,
Minnesota
Following is a list of the more Important activities:
1.

Geophysical work In connection with state-owned properties, or
along public roads to check possibilities for ore or rock materials, largely magnetic and resistivity surveys. Of special
Importance are areas south of the Iron formation Involving Cretaceous ore possIIiitiee, for example In the region between
Buhi end Kinney. Resistivity tests are uscful west of ovey
where the xnagietIc survey does not help, because of the nonmagnetic character of the iron formation.

2.

Exploration work on state permits and leases. This Includes
visual classification for separating the formatIon into Its
four main divisions and for sorting of ore materials Into mercharitable ore, wash ore, jig ore, and magnetic and non-magnetic
taconite. Stratigraphic work in the mines is also carried out.

3.

An important service is supplying Ir.formaion on drill records
and access to drill cores of work done on state lands. The
sample library at Hibbing supplements the U. S. Bureau of Mines
core library at Fort Snelling.

4.

Development of a circuit on the Dinge-Davis magnetic separator
permitting separation of samples Into high-grade concentrates,
magnetic middlings, arid non-magnetic tailings. This separation
facilitates microscopic and spectrographic examinations.

5.

Ground mapping of certain areas of state-owned land where
anomalies are shown by aerial magnetic surveys.

6.

Study of the Duluth gabbro contact areas of Interest for copper,
nickel, and other metals.

7.

Cooperation with various organizations in the preparation of
symposiums on mining and geology.

�UNIVERSITY OF MINNESOTA
Center for Continuation Study

Minneapolis

Institute

iL

April 1 —

on Lake Superior Geology

2, 19%

ORIGIN OF THE BIWABIK IRON—FORI&amp;ATION,
MESABI RANGE, MINNESOTA
D.

A. White

Carter Oil Company,

Tulsa, Oklahoma

The later Precambrian Animikie group in northeastern Minnesota consists
of three sedimentary units: the Pokegama (quartzite), Biwabik (iron—rich
rock), and Virginia (argillite) formations. "Mesabi range" designates the
preglacial outcrop belt,
to 3 miles wide and 120 miles long, of the
Biwabik formation.

Varieties of iron—rich rock ("taconite") are either granular or slaty
and consist dominantly of chert, iron silicates, magnetite, and siderite.
The Lower Cherty, Lower Slaty, Upper Cherty, and Upper Slaty members of
the Biwabik formation, which averages 600 feet in thickness, can be further
subdivided into smaller lithic units. These members are relatively uniform
along most of the range, but only one cherty and one slaty member exist on
the Westernmost Mesabi, where the lithic units are intertongued. The
Pokegama, Biwabik, and Virginia formations are considered conformable.
Chert, greenalite, ininnesotaite, stilpnomelane,
and siderite probably formed
rocks are essentially unmetamorphosed.

magnetite, some

hematite,
The

either during or shortly after deposition.

The Poke galna and

Biwabik formations were probably produced by the

migration of a series of coexisting environments of deposition during an
advance, a retreat, and a second advance of the Animikie sea. The deposits
formed,

during the retreat, in successive environments seaward from

shore,

were clastic material, carbonaceous—pyritic mud, chert—siderite, chert—
magnetite, and iron silicate. Fine clastics of the Virginia formation,
perhaps furnished by an outburst of volcanic activity, spread across the
former environments of chemical sedimentation. Possible conditions of iron
sedimentation were as follows: derivation of iron and silica by weathering
of a low—lying land mass, perhaps under an atmosphere rich in carbon dioxide,
and a seasonal climate; tectonic stability; and deposition in a shallow,
quiescent epicontinental sea.

�UNIVERSITY OF NNESCJIA

Center for Continuation Study
Minneapolis 14

April 1

Institute on Lake Superior Geolojr

2,

1955

SIJNMRY OF THE SUB—DIVISIONAL CORRELATION
OF THE MLDDLE HtJRONIAN IRON—FORMATIONS
OF THE LAKE SUPERIOR DISTRICT

J. F. Wolff, Sr.
Duluth, Minnesota

For a

generation or more there has been general agreement among
of the Lake Superior District, that, based on general geologic
associations, the major iron—ore producing formations of the (older)
Middle Huronian series of iron bearing rocks were of the same general
age and broadly of similar character.
geologists

A great many geologists have known, especially of later years, that

fairly comparable subdivisions of this Middle Huroniari iron—formation
can

be found

in the different districts.

The presenter of this brief contribution is not aware of the publication of any correlation diagram which shows major subdivision of the
older iron—formation of Mesabi, Cuyuna, Gogebic, Marquette and old Menominee
districts into four main layers and even the division of some of these
into minor layers having similar characteristics.
This contribution presents such a correlation diagram in color,
projected on a screen for convenience of the audience. Four major divisions
of the iron—formation are shown,—from the top down being — Upper Slaty,
Upper Cherty, Lower Slaty and Lower Cherty, lying between a basal quarteite
and quartz—slate and an overlying very thick black—slate and graywacke in
places, which locally has a conglomerate and quartzite—quartz—slate at its
base,
A very great erosion period intervened between the top of the Upper
Slaty and the beginning of deposition of the Upper Huronian conglomerate—
quartzite—slate series of rocks so that in places only remnants of the
Upper Slaty Division are left. In the main area of the Marquette District
there is no remnant of it so far as the writer knows but north of Crystal
Falls at the Arnasa—Porter mine,
was found at the top of the Negaunee
iron—formation.
A few of the minor subdivisions are shown on the diagram.

it

The major unconformity between Upper and Middle Huronlan rocks is
shown graphically, and the relative position of the Upper Huronian iron—
formations of the Iron River, Crystal Falls, Florence, Menominee, Marquette—
Gwinn, Gogebic and cuyuna districts is shown also on the diagram, which was
compiled from aU available sources, including the author's work or visits
in all the districts and interviews at different times with geologists
active in the several areas.

Minor details may be controversial especially with respect to the
greenstones in the Iron River, Crystal Falls and Florence districts whose
position in the geologic column may still be open to question and further
exploration evidence.

�UNIVERSITY OF MINNESOTA

Center for Continuation Study

Minneapolis l

Institute

April 1 —

on Lake Superior Geology

2, l9S

EXPLORATION FOR NICKEL AND
COPPER IN NORTHERN MINNESOTA

GEOCHB1'1ICAL

Donald H

University

of Minnesota,

Yardley

Minneapolis, Minnesota

Geochemical tests for nickel and copper in glacial soil from the Ely
district show that pronounced anomalies overlie mineralized Duluth gabbro
The geochemical pattern demonstrates that the mineralization is parallel
to the gabbro—granite contact, but 300 feet or so from the contact.

The

profiles of copper distribution are similar to the nickel profiles, with
copper present in greater amount.

Both metals are confined to the finer

soil fractions.

The processes by which the heavy elements migrate is not clear.

It

is believed that natural earth currents may play some part in distribution
of the heavy elements.

The vertical distribution is being tested to facili-

tate investigation of the process of migration.

�UNIVERSITY OF MINNESOTA
for Continuation Study
Minneapolis iL

Center

Institute

on Lake Superior Geolor

April 1 —

2, 19SS

STUDIES OF STRATIFIED ROCKS OCCURRING BELOW THE HtJRONIAN
SUCCESSION IN THE MARQUETTE DISTRICT, MICHIGAN

Justin Zinn, Gerald L Brooke,
Theodore Engel, and Richard Hagni
Michigan State College, East Lansing, Michigan

Several remnants of metamorphosed stratified rocks are known to occur
along the margin of the Marquette syncline or adjacent to nearb;,r Huronian

synclines in the Marquette district.

greater

These remnants are

age than the Mesnard quartzite

apparently all of

Three such remnants have been

restudied so far and they are the Lake 'nchantment (Mud Lake) sediments, the
Holyoke formation and the Kitchi schist.

The restudies included detailed

mapping and petrographic examination of the rocks of each area in the attempt
to eatablish more definitely the age and origin.
The Holyoke formation and the Lake Enchantment sediments overlie the
Keewatin greenstones with marked

tion

unconformable contacts and the Kitchi forma-

is believed to have a similar relationship.

belong

These formations therefore

to the time interval between the Keewatin and

in Michigan.

Each of these

sedimentary

the base of the Huronian

remnants is distinctly different

from the others and they are not believed to be of the same age.

The

Holyoke formation appears to be tillite and it may provide a clue in correlating

the Michigan Huronian with that on the north shore of Lake Huron.

�UNIVERSITY Oi MINNESOTA

Center for Continuation Study
Minneapolis iL'.

Institute

April

on Lake Superior Geology

1 — 2, 1955

BOTTOM CORING IN LAKE SUPERIOR

James H. Zuinberge

University
During

sediments

the

of Michigan, Ann

sruner of 1953

of Lake Superior.

several

Arbor, Michigan

cores were recovered from the

bottom

The research was accomplished through a coopera-

tive venture between the U. S. Fish and Wildlife Service and The Great Lakes
Research Institute, a research organization of the University of Michigan
dedicated to scientific investigations of the Great Lakes.
The cores were obtained with a gravity coring rig which consisted of a
weighted 5—foot length of 3—inch diameter pipe to which two 10—foot sections
of 2—inch I. D. diameter pipe was attached •

The maximum core recovery was

about 8 feet.

Ten cores were taken at Stations between Keweenaw Bay and Isle Royale,
and Grand Marais, Minnesota and Bayfield, Wisconsin.
fine grained ranging from clay to silt size.
cores is their color variation.

The core material is

The chief difference in the

Sortie are reddish, ranging from 10 R 3/2 to

2.5 YR 5/2 (Munsell), while others are grey.
is red and the lower 1 foot is grey.

In one core the upper 6 feet

No relationship between color and depth

of water or color and geographic location is apparent.
A mineralogical study of one core recovered in 630' of water showed that
the composition is about 75
clay minerals.

percent

quartz and feldspar and only 25 percent

The latter group include kaolinite and a possible interlayered

chiorite—illite mineral as indicated by X—ray diffraction studies presently
under way at Ohio State University.

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